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The price of elegance: Arsenic poisoning in the XIX century

Leopoldina
@leopoldina
10 years ago
280 posts

Translated from: diariosanacronicos.com/blog/o-preco-da-elegancia-intoxicacoes-por-arsenico-no-seculo-xix/

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Recently, the Bata Shoe Museum opened the exhibition "Fashion Victims: The Pleasures and Perils of Dress in the 19th Century". Beside addressing the highly important issue of the conditions of work that employees of the fashion industry were subjected , the exhibition brought light to information about the use oftoxicagents, specially for the fixation of textiles dyes, on that period.

TheLaundress_Jean-Baptiste_Greuze.jpg Until 1799, when Charles Tennant invented the bleach powder, white fabrics were obtained by the use of aged urine and used mainly for underwear. Despite theromanticismaround the figure of thelaundress in this XVIII century painting, there was nothing pretty in their craft.

The XIX century already starts with a valuable innovation in terms of textile technology. Thanks to the researches of Charles Tennant, who developed the bleach powder based on chlroine, it was possible to produce fabrics in what we call today off-white. Before this, the techniques of bleaching included the use of aged urine, in which the clothes were boiled and afterwards put to dry under the sun for hours. When we think about the Regency period (and in all of the movies based on Jane Austen's books) it's inevitable to remember the delicate white muslin dresses - that were accessible only a small part of the population. Both the technique of bleaching with chlorine as the traditional with urine involved complex chemical reactions with dangerous compounds, that directly affected the health of those involved in its washing and production. Blindness and chemical burns to the respiratory tract were some of the health problems faced by the workers of the white fabric industry in that period. But white was not even remotely the most dangeours tone to produce or wear.

DEATH IS GREEN AND NOT BECAUSE OF ABSINTHE

In 1775, the Swiss pharmacist Carl Wilhelm Scheele create a green pigment of high fixation, da upuntil the end of the XVIII century would replace all of the others. Its innovative formulation, however, hid a direct health risk, for the pigment's vibrant aspect and durability came from the combination of arsenic and copper sulfate. Due to its composition, the so-called "Scheele Green" tended to darken over time, which didn't stopped the spread of the dye in art, decor and clothing.

The Scheele Green was widely used in wallpapers, curtains, candles, cushions, artificial flowers, clothes and even as a food coloring. Among the workers who produced these pieces, and also between artists, arsenic poisonings were common and involved symptoms as dizziness (some researchers defend that the iconic figure of the fainting Victorian lady could have been originated of fainting caused by arsenic in wallpapers), loss of appetite, nausea, diarrhea, headache, irritability, convulsions and coma. The contact with arsenic is also linked to the development of malignant tumors and burns in the airways.

The arsenic wasabsorbedin three ways: throughinhalation(of candles or from wallpaper's dust), oral ingestion (in the case ofpaintersthat licked the brush's tip or children that, in 1850, died after eating candies dyed green) or through the skin. This direct contact with the skin was more common among the women, due to the sensation that the tones emerald-green caused in XIX century Europe. Taking in consideration that in 1860 there were already several publications denouncing the evils of green dyes, and other researchers continually tried to modify the original formula to make it less deadly, it is quite possible that people knew what awaited them when they decorated their mansion with green wallpaper. Still, these color's tones were so popular that ended up appearing even in satirical cartoons in the 1860s:

arsenic-waltz.jpg?width=400 "The Arsenic Waltz". Punch Maganize, 1860s.

The first modification to the original Scheele's formula was done in 1814, by two German pharmacists, who renamed their pigment as "emerald green". Cheaper than the Scheele Green, it soon integrated the English textile industry and began to be used indiscriminately in the dyeing of cotton. Moreover, it was also used in the production of glass and crystal (including those of domestic use, creating another way of poisoning), in the dyeing of leather, manufacture of soap, toy's painting, to color fireworks and even in the formula of poisons against rats.

2008BT5379_jpg_l.jpg?width=300 Wallpaper from the half of the XIX century, dyed with Emerald Green.

Collection of the Victoria & Albert Museum.

verde-esmeral-1860-5.jpg?width=400 Dress from 1860-1865 in emerald green. The possession of such assets require that the museum take special care in the storage and handling, to ensure the safety of employees.

The emerald green was also known as "Paris green" or "Vienna green" and its toxicity was only truly exposed in 1822, with the publication of its recipe. Amazingly, the use of this pigment was only definitively prohibited in the 1960s.

P88.43.1_20050527_01_web.jpg?width=400 Afternoon dress from the 1860s, dyed with an arsenic based pigment.

Collection of the FIT Museum.

Depiste of known toxicity of the green tones based on arsenic, these colors would only fall into disuse in decor from 1891, when Queen Victoria herself, warned by a foreign dignitary, had all of the green wallpaper in the Buckingham Palace to be removed, which was followed by her subjects.

jasminewallpaper_morris.jpg?width=400 Wallpaper form the collection of William Morris, c. 1840.

FUN FACT

The height concentrations of arsenic detected in the remains of Napoleon Bonaparte can be attributed to the fact that his residence in exile had several rooms with green wallpaper.

SOURCES:

http://twonerdyhistorygirls.blogspot.com.br/2010/06/deadly-shade-of-green.html

http://janeaustensworld.wordpress.com/2010/03/05/emerald-green-or-paris-green-the-deadly-regency-paint/

http://thepragmaticcostumer.wordpress.com/2014/06/11/drop-dead-gorgeous-a-tldr-tale-of-arsenic-in-victorian-life/

http://journals.ed.ac.uk/resmedica/article/viewFile/182/799

http://www.mnhs.org/preserve/conservation/reports/six_layer_sofa.pdf


updated by @leopoldina: 06 Oct 2016 06:29:53AM
Ekaterina Vorontsova-Dashkova
@ekaterina-vorontsova-dashkova
10 years ago
300 posts

I must say, this green *is* really nice to have. And yes, I do remember Napoleon's exile home on St. Elena in the mini-series "Napoleon". The room there was indeed such green. My, who would have thought the dye was that toxic. . . *stares at her green clothes in silence*

Sidonie Laborde
@sidonie-laborde
10 years ago
83 posts
Very interesting information, thanks Leo! Its odd to read that the horroble consequencese were known but ignored. But well thats fashion. Reminds me a bit of the troubles with the crinolines and bustles...I wonder if they decorated Napoleons exile in such greens for a reason. Hmmm....^^
Leopoldina
@leopoldina
10 years ago
280 posts

You're welcome! I read somewhere about the dangers of crinolines, with the difficulty of leaving a room in an emergency, drowning,etc, pretty scary lol.

I hope the translation was understandable enough! :p

Leopoldina
@leopoldina
10 years ago
280 posts

You're welcome :)

Leopoldina
@leopoldina
10 years ago
280 posts

more-you-know.gif?width=300

:p

Tiamat Windstorm von Hirvi
@tiamat-windstorm-von-hirvi
10 years ago
359 posts

And here I thought that occasional folk traditions of not wearing green were mere superstition. And I have so much green in my wardrobe...as does my lord...

So the recipe was published in 1822? That brings us a most interesting question. Given the extreme problems caused by Napoleon when he escaped from Elba, and the probability that some persons in the confidential services of the United Kingdom and other nations were well aware of the recipe in 1816, was the decoration of Napoleon's St. Helena rooms determined solely by someone's fondness for green, or by someone's practical political objectives?




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Antiquity Hedgewitch
Ekaterina Petrovna Shuvalova
@countess-shuvalova
10 years ago
209 posts

Green gown or survival? Hmmm well with the amount of lead powder on my face, and my breathing suffocated by a tight corset, the chances of me living long was already slim. GREEN GOWN IT IS.

Lorsagne de Sade
@lorsagne-de-sade
10 years ago
313 posts

This is fascinating. Thank you.

Leopoldina
@leopoldina
10 years ago
280 posts

hahaha yes! lol

Leopoldina
@leopoldina
10 years ago
280 posts

You're welcome!

Merry Chase
@merry-chase
10 years ago
154 posts

Fascinating!

Though it seems strange that people were so reluctant to give up the deadly green, here we are today, still denying the plausibility of danger from many known environmental toxins. I'm afraid human nature hasn't changed much!

Lorsagne de Sade
@lorsagne-de-sade
10 years ago
313 posts

So true! My jaw drops every time I see some one pay up to $7.00 USD for ONE package of cigarettes! To pay for the "right" to contract lung cancer? Insanity! But people will keep on doing it, bless their tiny little hearts for being unbelievably dumb about some things.